Structural and optical analysis of chalcogenide nanostructures

Authors

  • S. Chernkov National University of Science and Technology MISiS, 119049, Moscow, Leninsky Prospekt, 4, Russia Author
  • P. Badov Physics Department, University of Chemical Technology and Metallurgy, Sofia, Bulgaria Author

DOI:

https://doi.org/10.56053/3.2.197

Keywords:

Thin films, Chalcogenides, Optical transmission, Band gap

Abstract

Ultra-thin crystalline films of Bi-based chalcogenides were deposited with the aid of vacuum thermal evaporation technique. The influence of thermal annealing on the optical properties of Bi2Te3-Bi2Se3 films with different thicknesses has been investigate. Optical transmittance and reflectance of the as prepared and annealed films were measured in the wavelength range 290–2700 nm using a double beam spectrophotometer. Fundamental optical properties such as absorption coefficient and energy bend gap were derived based on the measured spectra and film’s thickness. We demonstrate in the present work that the synergy of annealing and thickness reduction can be exploited for light transmittance enhancements, and consequently optoelectronic applications including transparent electrode can be achieved.

References

-[1] A.Y. Morsy, S.S. Fouad, E. Hashem and A.A. EL-Shazly, ACTA PHYSICA POLONICA A, 80 (1991) 819

-[2] J. Dheepa, R. Sathyamoorthy, A. Subbarayan, Journal of Crystal Growth, (2005), 274, 100

-[3] V. Damorada Das, P. Gopal Ganesan, Semicond. Sci. Technol. 12 (1997) 195

-[4] S. Golia, M. Arora, R.K. Sharma, A.C. Rastogi, Curr. Appl. Phys. 3 (2003) 195

-[5] N.G. Patel, P.G. Patel, Solid State Electron. 35 (1992) 1269

-[6] S.A. Omer, U.G. Isifield, Solar Energy Mater. Solar Cell. 53 (1998) 67

-[7] J.C. Tedenac, S. Charar, Phys. Low Dimens. Struct. 5/6 (2000) 61

-[8] H.E.A. El-Sayed, Applied Surface Science 250 (2005) 70

-[9] A. Kadhim, A. Hmood, H. Abu Hassan, Materials Letters 65 (2011) 3105

-[10] J. Dheepa, R. Sathyamoorthy, S. Velumani, Materials Characterization, 58 (2007) 782

-[11] G. D. Deshmukh, S. M. Patil, S. S. Patil, and P. H. Pawar, JCBPS; Section C 5 (2015) 2769

-[12] G. Saffarini, J.M. Saiter, H. Schmitt, Opt. Mater. 29 (2007) 1143

-[13] J. Tauc, Amorphous and Liquid Semiconductors, Plenum, New York, (1979)

-[14] V. M. Garcıa, M. T. S. Nair, P. K. Nair, and R. A. Zingaro, Semiconductor Science and Technology 12 (1997) 645

-[15] Saji Augustine, Ampili S., Jeung Ku Kang and Elizabeth Mathai., Materials Research Bulletin 5 (2005) 1314

-[16] Shailaja Jeetendra, Naveen C. Shivappa, Raghu Patel, Mahesh H. Matt, "Optimization of Thickness of Sb2Te3 Thin Film as Back Contact for CdTe Thin Film Solar Cells", DOI: 10.5185/amlett.2014.7589, in press.

-[17] Liping Sun, Zhiqin Lin, Jian Peng, Jian Weng, Yizhong Huang, Zhengqian Luo, SCIENTIFIC REPORTS 4 (2014) 1

-[18] Farid M. Abdel-Rahim, M.M. Hafiz, H. Alsorory, Journal of Alloys and Compounds 570 (2013) 76

-[19] Brus, L. A simple model for the ionization potential, electron affinity, and aqueous redox potentials of small semiconductor crystallites. J. Chem. Phys. 79 (1983) 5566

-[20] Henglein, A. Small-particle research: physicochemical properties of extremely small colloidal metal and semiconductor particles. Chem. Rev. 89 (1989) 1861

-[21] M. Mourad Mabrook, Exp. Theo. NANOTECHNOLOGY 2 (2018) 103

-[22] Sandroff, C., Hwang, D. & Chung,W. Carrier confinement and special crystallite dimensions in layered semiconductor colloids. Phys. Rev. B 33 (1986) 5953

-[23] Smotkin, E. et al. Size quantization effects in cadmium sulfide layers formed by a Langmuir-Blodgett technique. Chem. Phys. Lett. 152 (1988) 265

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Published

2019-04-15

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How to Cite

Structural and optical analysis of chalcogenide nanostructures . (2019). Experimental and Theoretical NANOTECHNOLOGY, 3(2), 197-212. https://doi.org/10.56053/3.2.197