Green synthesis of CaO from eggshell waste and its impact on SiO2–Al2O3–B2O3 –NaF glass-ceramics nanostructure
DOI:
https://doi.org/10.56053/10.S.315Keywords:
Eggshells, CaO NPs, Glass-ceramic nanostructureAbstract
White eggshells are used as a natural precursor for the synthesis of calcium oxide (CaO NPs). A series of glass ceramic composite materials are then prepared by combining silicon dioxide (SiO2), aluminum oxide (Al2O3), boron oxide (B2O3), sodium fluoride (NaF), and calcium oxide (CaO) derived from eggshells. X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) are used to understand its effect. XRD analysis confirmed the successful synthesis of CaO NPs from eggshells with high purity. The XRD pattern showed peaks in the produced composite, which corresponds well with those of Si and also presence of quartz (SiO2). SEM image of composite samples reveals consistent spherical particle morphologies with size (30 to 60 nm). The FTIR spectra further verified the formation of CaO NPs also confirms the presence of compounds that used in synthesized composite. Peaks between 500-400 cm-1 indicates the existence of metal oxygen connections. Calcium oxide synthesis from eggshells and its effect on the structure of silicate glass ceramic composite properties.
Downloads
References
-[1] B.A.E. Ben-Arfa, I.M. Miranda Salvado, J.M.F. Ferreira, R.C. Pullar, Int. J. Appl. Glas Sci. 8 (2017) 337 https://doi.org/10.1016/j.msec.2018.05.016
-[2] M.S.K. Mubina, S. Shailajha, R. Sankaranarayanan, L. Saranya, J. Mech. Behav. Biomed. Mater. 100 (2019) 103379 https://doi.org/10.1016/j.jmbbm.2019.103379
-[3] R.H. Hassan, D.K. Mahdi, Iraqi J. Phys. 22 (2024) 104 https://doi.org/10.30723/tfm9wa89
-[4] M. Riaz, R. Zia, F. Saleemi, H. Ikram, F. Bashir, J. Mater. Sci. Mater. Med. 26 (2015) 1 https://doi.org/10.1007/s10856-015-5603-3
-[5] H. Fujita, H. Iida, K. Ido, Y. Matsuda, M. Oka, T. Nakamura, J. Bone Joint Surg. Br. 82 (2000) 614 https://doi.org/10.1302/0301-620X.82B4.0820614
-[6] T.A. Kareem, D.K. Mahdi, Eurasian Chem. Commun. 4 (2022) 330 https://doi.org/10.22034/ecc.2022.326506.1311
-[7] S.M. Salman, S.N. Salama, H. Darwish, H.A. Abo-Mosallam, Ceram. Int. 35 (2009) 1083 https://doi.org/10.1016/j.ceramint.2008.04.025
-[8] K. Adaikalam, A.M. Teli, K.P. Marimuthu, S. Ramesh, H. Lee, H.S. Kim, et al., Nanomaterials 14 (2024) 1129 https://doi.org/10.3390/nano14131129
-[9] M.Y. Chou, T.A. Lee, Y.S. Lin, S.Y. Hsu, M.F. Wang, P.H. Li, et al., Sci. Rep. 13 (2023) 437 https://doi.org/10.1038/s41598-023-27682-5
-[10] Y.C. Wong, R.X. Ang, Open Chem. 16 (2018) 1166 https://doi.org/10.1515/chem-2018-0127
-[11] A. Anantharaman, S. Ramalakshmi, M. George, Int. J. Eng. Res. Appl. 6 (2016) 27 https://doi.org/10.1038/s41598-022-06981-3
-[12] K. Adaikalam, S. Hussain, P. Anbu, A. Rajaram, I. Sivanesan, H.S. Kim, Nanomaterials 14 (2024) 1620 https://doi.org/10.3390/nano14201620
-[13] J.A. Tavizón-Pozos, H. Cervantes-Cuevas, G.G. Garcia-Camacho, G. Chavez-Esquivel, D.R. Acosta-Najarro, ACS Omega 10 (2025) 6827 https://doi.org/10.1021/acsomega.4c09118
-[14] T.A.E. Ahmed, L. Wu, M. Younes, M. Hincke, Front. Bioeng. Biotechnol. 9 (2021) 675364 https://doi.org/10.3389/fbioe.2021.675364
-[15] A.Z. Jaji, M.Z.B.A. Bakar, R. Mahmud, M.Y. Loqman, M.N.M. Hezmee, T. Isa, et al., Nanotechnol. Sci. Appl. 10 (2017) 23 https://doi.org/10.2147/NSA.S113030
-[16] S. Maleki, M. Barzegar-Jalali, M.H. Zarrintan, K. Adibkia, F. Lotfipour, Pharm. Sci. 20 (2015) 175 https://doi.org/10.1038/s41598-020-75454-2
-[17] O.V. Kharissova, H.V.R. Dias, B.I. Kharisov, B.O. Pérez, V.M.J. Pérez, Trends Biotechnol. 31 (2013) 240 https://doi.org/10.1016/j.tibtech.2013.01.003
-[18] R. Mohadi, A. Sueb, K. Anggraini, A. Lesbani, J. Pure Appl. Chem. Res. 7 (2018) 130 https://doi.org/10.21776/ub.jpacr.2018.007.02.390
-[19] V. Bhuvaneshwari, S. Sonia, D. Sivaganesh, Chem. Phys. Impact 9 (2024) 100699 https://doi.org/10.1016/j.chphi.2024.100699
-[20] N. Ojha, I. Dmitrieva, W. Blanc, L. Petit, Ceramics 4 (2021) 148 https://doi.org/10.3390/ceramics4020013
-[21] Z. Zhang, H. Ma, C. Wu, Y. Sun, R. Chen, X. Guo, Separations 10 (2023) 498 https://doi.org/10.3390/separations10090498
-[22] S. Rujitanapanich, P. Kumpapan, P. Wanjanoi, Energy Procedia 56 (2014) 112 https://doi.org/10.1016/j.egypro.2014.07.138
-[23] N.O. Eddy, J. Oladede, I.S. Eze, R. Garg, R. Garg, H. Paktin, Results Eng. 24 (2024) 103374 https://doi.org/10.1016/j.rineng.2024.103374
-[24] A. Roy, J. Bhattacharya, Nanotechnol. 3 (2011) 565 https://doi.org/10.1016/j.rio.2024.100677
-[25] A.M. Elbarbary, M.A. Elhady, Y.H. Gad, J. Inorg. Organomet. Polym. Mater. 32 (2022) 4039 https://doi.org/10.1007/s10904-022-02395-w
-[26] Y. Lu, Y. Shan, X. Guo, Y. Zhang, J. Feng, H. Zhou, J. Mater. Sci. Mater. Electron. 34 (2023) 443 https://doi.org/10.1007/s10854-023-09902-w
-[27] J. Li, Y. Wu, Y. Pan, W. Liu, J. Guo, Ceram. Int. 33 (2007) 919 https://doi.org/10.1016/j.ceramint.2006.02.002
-[28] N. Yamaguchi, Y. Masuda, Y. Yamada, H. Narusawa, H.-C. Han, Y. Tamaki, et al., Open J. Inorg. Non-Metallic Mater. 5 (2014) 1 https://doi.org/10.2298/PAC2202115T
-[29] A. Behairy, New J. Glas Ceram. 9 (2019) 15 https://doi.org/10.1007/s13369-024-08988-6
-[30] A. Abd El-Moneim, H.A. Hashem, A.A. El-Namrouty, A. Atef, J. Non-Cryst. Solids 580 (2022) 121389 https://doi.org/10.1016/j.jnoncrysol.2021.121389
-[31] W. Zheng, J.M. Wu, S. Chen, C.S. Wang, C.L. Liu, S.B. Hua, et al., J. Adv. Ceram. 10 (2021) 1381 https://doi.org/10.1007/s40145-021-0513-y
-[32] J.M. Oliveira, R.N. Correia, M.H. Fernandes, J. Non-Cryst. Solids 273 (2000) 59 https://doi.org/10.1016/S0022-3093(00)00144-7
-[33] D.P. Mukherjee, S.K. Das, Ceram. Int. 39 (2013) 571 https://doi.org/10.1016/j.ceramint.2012.06.066
-[34] M. M. Abbas, M. Rasheed, J. Phys. Conf. Ser., 1795(1) (2021) 012059 https://doi.org/10.1088/1742-6596/1795/1/012059.
-[35] P.Y. Shi, M.F. Jiang, C.J. Liu, D.Y. Wang, J. Northeast Univ. (Nat. Sci.) 25 (2004) 866 https://doi.org/10.1044/jshd.2404.330
-[36] A. Khan, S.T. Hussain, A. Naeem, A. Sadiqa, A. Ahmad, M.A.A. Shehzada, et al., Results Chem. 12 (2025) 102073 https://doi.org/10.3390/catal15100970
-[37] M. Rasheed, SuhaShihab, O. Alabdali, H. H. Hassan, J. Phys. Conf. Ser., 1879(3) (2021) 032113 https://doi.org/10.1088/1742-6596/1879/3/032113.
-[38] D. MEKAM, D. MESRI , H. Rozale. Experimental and Theoretical NANOTECHNOLOGY, 3(3) (2019) 281 https://doi.org/10.56053/3.3.281.
-[39] I. Fatimah, G.R. Aulia, W. Puspitasari, R. Nurillahi, L. Sopia, R. Herianto, Sustain. Environ. Res. 28 (2018) 462 https://doi.org/10.1016/j.serj.2018.10.003
-[40] A.J. Hussein, M.N. Al-Darraji, M. Rasheed, M.A. Sarhan, IOP Conf. Ser.: Earth Environ. Sci. 1262 (2023) 022005 https://doi.org/10.1088/1755-1315/1262/2/022005.
-[41] A.I. Hussein, Z. Ab-Ghani, A.N. Che Mat, N.A. Ab Ghani, A. Husein, I. Ab. Rahman, Appl. Sci. 10 (2020) 7170 https://doi.org/10.3390/app10207170
-[42] T. Saidani, M. Rasheed, I. Alshalal, A.A. Rashed, M.A. Sarhan, R. Barillé, Res. Eng. Struct. Mater. 10 (2) (2024) 743 http://dx.doi.org/10.17515/resm2023.21ma0922rs.
-[43] F. Dai, Q. Zhuang, G. Huang, H. Deng, X. Zhang, ACS Omega 8 (2023) 17064 https://doi.org/10.1021/acsomega.3c01336
-[44] M. A. Sarhan, S. Shihab, B. E. Kashem, M. Rasheed, J. Phy.: Conf. Ser., 1879(2) (2021) 022122 https://doi.org/10.1088/1742-6596/1879/2/022122.
-[45] I. León, R. Montero, A. Longarte, J.A. Fernández, J. Phys. Chem. Lett. 12 (2021) 1316 https://doi.org/10.1021/acs.jpclett.0c03001
-[46] S. Mukherjee, S. Das, S. Nuthi, C.R. Patra, Future Sci. OA 3 (2017) FSO233 https://doi.org/10.4155/fsoa-2017-0048
-[47] J. Anastassopoulou, P. Kolovou, P. Papagelopoulos, T. Theophanides, Infrared Spectrosc. Life Biomed. Sci. 25 (2012) 259 https://doi.org/10.1038/s41598-021-86257-4
-[48] S. Mondal, A.K. Banthia, J. Eur. Ceram. Soc. 25 (2005) 287 https://doi.org/10.1016/j.jeurceramsoc.2004.08.011
-[49] A. M. Shehap, Kh.H. Mahmoud, M.F.H. Abdelkader, Tarek M. El-Basheer, Experimental and Theoretical NANOTECHNOLOGY 1 (2017) 103 https://doi.org/10.56053/1.2.103.
-[50] P.A. Bhat, N.C. Debnath, IOP Conf. Ser.: Mater. Sci. Eng. 53 (2013) 012001 https://doi.org/10.1021/acssusresmgt.5c00359
